MISC

2005年6月

The effect of fluoromethyl groups on the diastereoselectivity in the electrophilic alkylation

JOURNAL OF FLUORINE CHEMISTRY
  • K Tamura
  • ,
  • T Yamazaki
  • ,
  • T Kitazume
  • ,
  • T Kubota

126
6
開始ページ
918
終了ページ
930
記述言語
英語
掲載種別
DOI
10.1016/j.jfluchem.2005.04.001
出版者・発行元
ELSEVIER SCIENCE SA

The effect of fluoromethyl groups on the diastereoselectivity in the electrophilic alkylation is described. In particular, the electrophilic alkylation of enolates with a trifluoromethyl group was proceeded with highly diastereofacial selectivity based on the steric and/or electrostatic effect of substituent with strong electron withdrawing. (C) 2005 Published by Elsevier B.V.

リンク情報
DOI
https://doi.org/10.1016/j.jfluchem.2005.04.001
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000230574500009&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.jfluchem.2005.04.001
  • ISSN : 0022-1139
  • Web of Science ID : WOS:000230574500009

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