2017年3月
Freezing-point Depression of Benzene Confined in Mesoporous Silica SBA-15 on Doping with a Slight Amount of Toluene: Ideal Behavior in a Nanometer-sized Space
CHEMISTRY LETTERS
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- 巻
- 46
- 号
- 3
- 開始ページ
- 296
- 終了ページ
- 298
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.161029
- 出版者・発行元
- CHEMICAL SOC JAPAN
We introduced benzene-toluene solution into the pores of the mesoporous silica material SBA-15 and investigated its fusion behavior using differential scanning calorimetry. On introduction into the pores, the concentration of the solution did not change. The introduced solution exhibited typical behavior of freezing-point depression upon the addition of a toluene component. We discuss this behavior and the large value of the slope of a plot of the fusion temperature of benzene in a confined sample against the logarithm of the molar fraction of benzene.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.161029
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000393524700004