2014年7月
Csp(3)-Csp(3) Homocoupling Reaction of Benzyl Halides Catalyzed by Rhodium
ORGANIC LETTERS
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- 巻
- 16
- 号
- 14
- 開始ページ
- 3756
- 終了ページ
- 3759
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/ol501619w
- 出版者・発行元
- AMER CHEMICAL SOC
A highly reactive alkylrhodium complex was formed from Me2Zn and RhCl(PPh3)(3) and effectively catalyzed a Csp(3)-Csp(3) homocoupling reaction of benzyl halides. A Csp(3)-Csp(3) coupling reaction using Rh catalyst has not been reported up to now. The reaction proceeded under very mild conditions and gave the corresponding homocoupling products even if they had reactive substituents such as an uncovered formyl or hydroxymethyl group.
- リンク情報
- ID情報
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- DOI : 10.1021/ol501619w
- ISSN : 1523-7060
- eISSN : 1523-7052
- Web of Science ID : WOS:000339367300037