2015年
One-pot synthesis of 1,3-enynes with a CF3 group on the terminal sp(2) carbon by an oxidative Sonogashira cross-coupling reaction
ORGANIC & BIOMOLECULAR CHEMISTRY
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- 巻
- 13
- 号
- 33
- 開始ページ
- 8886
- 終了ページ
- 8892
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c5ob01290b
- 出版者・発行元
- ROYAL SOC CHEMISTRY
Oxidative Sonogashira cross-coupling reactions of (E)-trimethyl(3,3,3-trifluoroprop-1-enyl) silane with arylacetylene were achieved using silver fluoride and a palladium catalyst, to afford high yields of various 1,3-enynes with a CF3 group on the terminal sp(2) carbon. Silver fluoride promoted C-Si bond dissociation and oxidation of palladium, enabling catalytic use of palladium.
- リンク情報
- ID情報
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- DOI : 10.1039/c5ob01290b
- ISSN : 1477-0520
- eISSN : 1477-0539
- Web of Science ID : WOS:000359458700013