Misc.

Mar, 2001

Direct observation of 2-(1-methoxycarbonylnaphthyl)methyl radical via photo-Claisen type rearrangement

CHEMISTRY LETTERS
  • Y Yoshimi
    • ,
  • K Mizuno
    • ,
  • H Maeda
    • ,
  • M Ichinose
    • ,
  • T Tanaka
    • ,
  • S Kawanishi
Volume
No. 3, 252-253.
Number
3
First page
252
Last page
253
Language
English
Publishing type
DOI
10.1246/cl.2001.252
Publisher
CHEMICAL SOC JAPAN
The photo-Claisen type rearrangement of 2-(1-methoxycarbonylnaphthyl)methyl phenyl ether derivatives 1a-f was investigated. The 2-( 1-methoxycarbonylnaphthyl)methyl radical and its fluorescence by use of two colored laser flash photolysis (LFP) technique were directly observed as a reactive intermediate. The reactivity of the photorearrangement depended on the p-substituents on the phenoxy group.
Link information
DOI
https://doi.org/10.1246/cl.2001.252
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000167818400034&DestApp=WOS_CPL
ID information
  • DOI : 10.1246/cl.2001.252
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • Web of Science ID : WOS:000167818400034
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