2001年12月
Intrinsic localized vibrational modes in a highly nonlinear halogen-bridged metal
JOURNAL OF LUMINESCENCE
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- 巻
- 94
- 号
- 開始ページ
- 743
- 終了ページ
- 746
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- 出版者・発行元
- ELSEVIER SCIENCE BV
Intrinsic localized vibrational modes in a halogen-bridged Pt complex were studied by Raman spectroscopy. We compared the peak frequency of the overtone of Pt-Cl stretch vibration between that excited by an Ar+ and that by a near infrared (NIR) lasers. The decrease in the overtone peak frequency of the NIR excitation were larger than that of the visible excitation. We interpreted that the charge transfer led to weaken the bond strength and that the anharmonicity of the system became weak. (C) 2001 Elsevier Science B.V. All rights reserved.
- リンク情報
- ID情報
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- ISSN : 0022-2313
- Web of Science ID : WOS:000172944700151