2004年12月
Cobalt-mediated Mizoroki-Heck-type reaction of epoxide with styrene
ADVANCED SYNTHESIS & CATALYSIS
- ,
- ,
- ,
- 巻
- 346
- 号
- 13-15
- 開始ページ
- 1631
- 終了ページ
- 1634
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/adsc.200404074
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Treatment of a mixture of epoxide and styrene with trimethylsilylmethylmagnesium bromide in the presence of a cobalt-phosphine complex afforded homocinnamyl alcohol in good yield. The reaction should begin with ring opening of the epoxide by the action of magnesium bromide which leads to the formation of a magnesium 2-bromoethoxide derivative and not with a direct single electron transfer from a cobalt complex to the epoxide.
- リンク情報
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- DOI
- https://doi.org/10.1002/adsc.200404074
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902268983690720
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000225985800010&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
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- DOI : 10.1002/adsc.200404074
- ISSN : 1615-4150
- J-Global ID : 200902268983690720
- ORCIDのPut Code : 27822203
- Web of Science ID : WOS:000225985800010