2005年8月
Gallium-mediated allyl transfer from bulky homoallylic alcohol to aldehydes via retro-allylation: Stereoselective synthesis of both erythro- and threo-homoallylic alcohols
ORGANIC LETTERS
- ,
- ,
- ,
- 巻
- 7
- 号
- 16
- 開始ページ
- 3577
- 終了ページ
- 3579
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/ol0515199
- 出版者・発行元
- AMER CHEMICAL SOC
Retro-allylation of bulky gallium homoallylic alkoxides occurs to generate (Z)- and (E)-crotylgallium reagents stereospecifically, starting from erythro- and threo-homoallylic alcohols, respectively. The (Z)- and (E)-crotylgallium reagents immediately reacted with aromatic aldehydes to afford the corresponding erythro- and threo-homoallylic alcohols, respectively.
- リンク情報
-
- DOI
- https://doi.org/10.1021/ol0515199
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902231832606158
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/16048346
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000230858500047&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
-
- DOI : 10.1021/ol0515199
- ISSN : 1523-7060
- eISSN : 1523-7052
- J-Global ID : 200902231832606158
- ORCIDのPut Code : 27822185
- PubMed ID : 16048346
- Web of Science ID : WOS:000230858500047