2006年2月
New synthetic reactions catalyzed by cobalt complexes
PURE AND APPLIED CHEMISTRY
- ,
- 巻
- 78
- 号
- 2
- 開始ページ
- 441
- 終了ページ
- 449
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1351/pac200678020441
- 出版者・発行元
- INT UNION PURE APPLIED CHEMISTRY
Without suffering from beta-elimination, cobalt complexes allow cross-coupling reactions of alkyl halides with Grignard reagents. A combination of a cobalt complex and trimethylsilylmethyl Grignard reagent effects Mizoroki-Heck-type reaction of alkyl halide with styrene, which conventional palladium catalysts have never made possible. Cobalt exhibits intriguing catalytic activities on hydrophosphination and allylzincation of alkynes. Silylmethylcobalt reagent is a powerful tool for the synthesis of highly silylated ethenes.
- リンク情報
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- DOI
- https://doi.org/10.1351/pac200678020441
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902210762000454
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000235784500030&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
-
- DOI : 10.1351/pac200678020441
- ISSN : 0033-4545
- J-Global ID : 200902210762000454
- ORCIDのPut Code : 27822162
- Web of Science ID : WOS:000235784500030