2008年4月
Synthesis of arylallenes by palladium-catalyzed retro-propargylation of homopropargyl alcohols
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ,
- ,
- ,
- 巻
- 130
- 号
- 15
- 開始ページ
- 5048
- 終了ページ
- +
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/ja800986m
- 出版者・発行元
- AMER CHEMICAL SOC
Treatment of tertiary homopropargyl alcohol with aryl halide under palladium catalysis provided arylallenes regioselectively. The reaction includes retropropargylation, which proceeds in a concerted fashion via a cyclic transition state and transfers the stereochemistry of homopropargyl alcohols through C-C bond cleavage. The present method enables the use of homopropargyl alcohols as allenylmetal equivalents.
- リンク情報
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- DOI
- https://doi.org/10.1021/ja800986m
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902272924250552
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/18348523
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000254933000024&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
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- DOI : 10.1021/ja800986m
- ISSN : 0002-7863
- J-Global ID : 200902272924250552
- ORCIDのPut Code : 27822030
- PubMed ID : 18348523
- Web of Science ID : WOS:000254933000024