2009年8月
Synthesis of (2-Arylethylidene)cyclobutanes by Palladium-Catalyzed Reactions of Aryl Halides with Homoallyl Alcohols Bearing a Trimethylene Group at the Allylic Position
SYNLETT
- ,
- ,
- 巻
- 号
- 13
- 開始ページ
- 2177
- 終了ページ
- 2179
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1055/s-0029-1217703
- 出版者・発行元
- GEORG THIEME VERLAG KG
Treatment of aryl bromides with homoallyl alcohols bearing a trimethylene group at the allylic position in the presence of cesium carbonate tinder palladium catalysis affords (2-aryl-ethylidene)cyclobutanes selectively. The selective formation of the alkylidenecyclobutane skeleton results from regiospecific retro-allylation of the homoallyl alcohols, which accompanies the transposition of the double bonds.
- リンク情報
-
- DOI
- https://doi.org/10.1055/s-0029-1217703
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902224327739422
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000269217900027&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
-
- DOI : 10.1055/s-0029-1217703
- ISSN : 0936-5214
- J-Global ID : 200902224327739422
- ORCIDのPut Code : 27821952
- Web of Science ID : WOS:000269217900027