2009年9月
Copper-Catalyzed Allylation of Alkyl Halides with Allylic Grignard Reagents
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- ,
- ,
- 巻
- 82
- 号
- 9
- 開始ページ
- 1194
- 終了ページ
- 1196
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/bcsj.82.1194
- 出版者・発行元
- CHEMICAL SOC JAPAN
Treatment of alkyl halides, including secondary and tertiary alkyl bromides, with allylic Grignard reagents in the presence of a catalytic amount of copper(II) triflate in diisopropyl ether at 25 degrees C yielded the corresponding allylated products in high yields. The coupling reactions of tertiary alkyl halides lead to construction of allylated quaternary carbon centers. The active species is likely to be allylcuprate.
- リンク情報
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- DOI
- https://doi.org/10.1246/bcsj.82.1194
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902234078749825
- CiNii Articles
- http://ci.nii.ac.jp/naid/10025322159
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000271497600016&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
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- DOI : 10.1246/bcsj.82.1194
- ISSN : 0009-2673
- eISSN : 1348-0634
- J-Global ID : 200902234078749825
- CiNii Articles ID : 10025322159
- ORCIDのPut Code : 27821937
- Web of Science ID : WOS:000271497600016