2009年11月
Radical Addition of Polyhaloalkanes to 2-Ethynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
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- 巻
- 82
- 号
- 11
- 開始ページ
- 1433
- 終了ページ
- 1435
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1246/bcsj.82.1433
- 出版者・発行元
- CHEMICAL SOC JAPAN
Radical addition of bromotrichloromethane to 2-ethynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane takes place in the presence of a radical initiator in refluxing benzene. Perfluoroalkyl iodides undergo similar addition reactions. The addition reactions proceed in an anti fashion. The corresponding 1-halo-1-alkenylboronic esters are useful intermediates that undergo cross-coupling reactions.
- リンク情報
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- DOI
- https://doi.org/10.1246/bcsj.82.1433
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902222062741966
- CiNii Articles
- http://ci.nii.ac.jp/naid/10027170437
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000273024400013&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
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- DOI : 10.1246/bcsj.82.1433
- ISSN : 0009-2673
- eISSN : 1348-0634
- J-Global ID : 200902222062741966
- CiNii Articles ID : 10027170437
- ORCIDのPut Code : 27821948
- Web of Science ID : WOS:000273024400013