2009年9月
Synthesis of Aryliron Complexes [CpFe(CO)(2)Ar] by Palladium-Catalyzed Reactions of [CpFe(CO)(2)I] with Arylzinc, -Boron, or -Indium Reagents
MATERIALS
- ,
- ,
- ,
- 巻
- 2
- 号
- 3
- 開始ページ
- 978
- 終了ページ
- 991
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.3390/ma2030978
- 出版者・発行元
- MDPI AG
Transmetalation between [CpFe(CO)(2)I] and arylzinc iodide-lithium chloride complexes proceeds in the presence of catalytic amounts of palladium acetate and N,N,N',N'-tetramethyl-1,2-cyclohexanediamine to yield the corresponding aryliron complexes [CpFe(CO)(2)Ar]. Phenylation of [CpFe(CO)(2)I] also takes place when triphenylindium is used under similar conditions. Arylboronic acids undergo arylation in the presence of cesium carbonate and a palladium-N-heterocyclic carbene complex, PEPPSI. The present methods are useful for the facile synthesis of various functionalized [CpFe(CO)(2)Ar]. The products [CpFe(CO)(2)Ar] represent an interesting class of aryl metals that undergo several transformation.
- リンク情報
-
- DOI
- https://doi.org/10.3390/ma2030978
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201502803350398788
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000208140000019&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
-
- DOI : 10.3390/ma2030978
- ISSN : 1996-1944
- J-Global ID : 201502803350398788
- ORCIDのPut Code : 27821953
- Web of Science ID : WOS:000208140000019