論文

査読有り
2009年9月

Synthesis of Aryliron Complexes [CpFe(CO)(2)Ar] by Palladium-Catalyzed Reactions of [CpFe(CO)(2)I] with Arylzinc, -Boron, or -Indium Reagents

MATERIALS
  • Shigeo Yasuda
  • ,
  • Yoshihiro Asada
  • ,
  • Hideki Yorimitsu
  • ,
  • Koichiro Oshima

2
3
開始ページ
978
終了ページ
991
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.3390/ma2030978
出版者・発行元
MDPI AG

Transmetalation between [CpFe(CO)(2)I] and arylzinc iodide-lithium chloride complexes proceeds in the presence of catalytic amounts of palladium acetate and N,N,N',N'-tetramethyl-1,2-cyclohexanediamine to yield the corresponding aryliron complexes [CpFe(CO)(2)Ar]. Phenylation of [CpFe(CO)(2)I] also takes place when triphenylindium is used under similar conditions. Arylboronic acids undergo arylation in the presence of cesium carbonate and a palladium-N-heterocyclic carbene complex, PEPPSI. The present methods are useful for the facile synthesis of various functionalized [CpFe(CO)(2)Ar]. The products [CpFe(CO)(2)Ar] represent an interesting class of aryl metals that undergo several transformation.

リンク情報
DOI
https://doi.org/10.3390/ma2030978
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201502803350398788
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000208140000019&DestApp=WOS_CPL
URL
http://orcid.org/0000-0002-0153-1888
ID情報
  • DOI : 10.3390/ma2030978
  • ISSN : 1996-1944
  • J-Global ID : 201502803350398788
  • ORCIDのPut Code : 27821953
  • Web of Science ID : WOS:000208140000019

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