論文

査読有り
2011年2月

Cobalt-Catalyzed Addition of Styrylboronic Acids to 2-Vinylpyridine Derivatives

CHEMISTRY-AN ASIAN JOURNAL
  • Tsuneyuki Kobayashi
  • ,
  • Hideki Yorimitsu
  • ,
  • Koichiro Oshima

6
2
開始ページ
669
終了ページ
673
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/asia.201000275
出版者・発行元
WILEY-V C H VERLAG GMBH

Treatment of 2-vinyl nitrogen-containing heteroaromatic compounds with styrylboronic acid in the presence of a cobalt catalyst and a base results in an addition reaction to afford the corresponding 4-phenyl-3-butenyl heteroarenes. The adjacent nitrogen atom is essential for the promotion of the reaction because the nitrogen accelerates the addition of the styryl cobalt species, generated by transmetalation, onto the vinyl group. The reaction represents a rare example of cobalt catalysis in the reactions of organoboronic acids.

リンク情報
DOI
https://doi.org/10.1002/asia.201000275
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201102291579177416
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/20665650
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000286440600054&DestApp=WOS_CPL
URL
http://orcid.org/0000-0002-0153-1888
ID情報
  • DOI : 10.1002/asia.201000275
  • ISSN : 1861-4728
  • J-Global ID : 201102291579177416
  • ORCIDのPut Code : 27821898
  • PubMed ID : 20665650
  • Web of Science ID : WOS:000286440600054

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