2011年2月
Cobalt-Catalyzed Addition of Styrylboronic Acids to 2-Vinylpyridine Derivatives
CHEMISTRY-AN ASIAN JOURNAL
- ,
- ,
- 巻
- 6
- 号
- 2
- 開始ページ
- 669
- 終了ページ
- 673
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/asia.201000275
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Treatment of 2-vinyl nitrogen-containing heteroaromatic compounds with styrylboronic acid in the presence of a cobalt catalyst and a base results in an addition reaction to afford the corresponding 4-phenyl-3-butenyl heteroarenes. The adjacent nitrogen atom is essential for the promotion of the reaction because the nitrogen accelerates the addition of the styryl cobalt species, generated by transmetalation, onto the vinyl group. The reaction represents a rare example of cobalt catalysis in the reactions of organoboronic acids.
- リンク情報
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- DOI
- https://doi.org/10.1002/asia.201000275
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201102291579177416
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/20665650
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000286440600054&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
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- DOI : 10.1002/asia.201000275
- ISSN : 1861-4728
- J-Global ID : 201102291579177416
- ORCIDのPut Code : 27821898
- PubMed ID : 20665650
- Web of Science ID : WOS:000286440600054