2012年6月
Synthesis of 1,2-Disubstituted Cyclopentenes by Palladium-Catalyzed Reaction of Homopropargyl-Substituted Dicarbonyl Compounds with Organic Halides via 5-Endo-Dig Cyclization
ORGANIC LETTERS
- ,
- ,
- 巻
- 14
- 号
- 11
- 開始ページ
- 2914
- 終了ページ
- 2917
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ol301257m
- 出版者・発行元
- AMER CHEMICAL SOC
Palladium catalysts with bulky biaryl phosphine ligands allow homopropargyl-substituted dicarbonyl compounds to undergo intramolecular addition via a rare 5-endo-dig pathway. C-C bond forming reductive elimination follows the addition to Introduce alkenyl and alkynyl as well as aryl groups by using the corresponding organic halides. The cyclization is versatile enough to be applicable to the synthesis of highly substituted dihydropyrrole and a fused tricyclic compound.
- リンク情報
-
- DOI
- https://doi.org/10.1021/ol301257m
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201202224985933300
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/22612561
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000304682700066&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
-
- DOI : 10.1021/ol301257m
- ISSN : 1523-7060
- J-Global ID : 201202224985933300
- ORCIDのPut Code : 27821878
- PubMed ID : 22612561
- Web of Science ID : WOS:000304682700066