論文

査読有り
2013年4月

Direct Arylation of Porphyrins with pi-Extended Aryl Bromides under Ligand-free Fagnou-Hartwig Conditions

ASIAN JOURNAL OF ORGANIC CHEMISTRY
  • Yutaro Yamamoto
  • ,
  • Sumito Tokuji
  • ,
  • Takayuki Tanaka
  • ,
  • Hideki Yorimitsu
  • ,
  • Atsuhiro Osuka

2
4
開始ページ
320
終了ページ
324
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/ajoc.201200198
出版者・発行元
WILEY-V C H VERLAG GMBH

Palladium-catalyzed direct beta-diarylation of the nickel complexes of 5,10,15-triarylporphyrins with pi-extended aryl bromides, such as 9-bromoanthracene, is described. The reaction proceeded in N,N-dimethylacetamide in the presence of potassium carbonate, pivalic acid, and a catalytic amount of palladium acetate without any additional ligands. The absorption and emission properties as well as X-ray crystallographic analysis of the arylated porphyrins are also discussed.

リンク情報
DOI
https://doi.org/10.1002/ajoc.201200198
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201702213095175609
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000325987500008&DestApp=WOS_CPL
URL
http://orcid.org/0000-0002-0153-1888
ID情報
  • DOI : 10.1002/ajoc.201200198
  • ISSN : 2193-5807
  • eISSN : 2193-5815
  • J-Global ID : 201702213095175609
  • ORCIDのPut Code : 27821851
  • Web of Science ID : WOS:000325987500008

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