2013年4月
Direct Arylation of Porphyrins with pi-Extended Aryl Bromides under Ligand-free Fagnou-Hartwig Conditions
ASIAN JOURNAL OF ORGANIC CHEMISTRY
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- ,
- ,
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- 巻
- 2
- 号
- 4
- 開始ページ
- 320
- 終了ページ
- 324
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/ajoc.201200198
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Palladium-catalyzed direct beta-diarylation of the nickel complexes of 5,10,15-triarylporphyrins with pi-extended aryl bromides, such as 9-bromoanthracene, is described. The reaction proceeded in N,N-dimethylacetamide in the presence of potassium carbonate, pivalic acid, and a catalytic amount of palladium acetate without any additional ligands. The absorption and emission properties as well as X-ray crystallographic analysis of the arylated porphyrins are also discussed.
- リンク情報
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- DOI
- https://doi.org/10.1002/ajoc.201200198
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201702213095175609
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000325987500008&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
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- DOI : 10.1002/ajoc.201200198
- ISSN : 2193-5807
- eISSN : 2193-5815
- J-Global ID : 201702213095175609
- ORCIDのPut Code : 27821851
- Web of Science ID : WOS:000325987500008