2014年10月
Palladium-Catalyzed Cross-Coupling of Unactivated Aryl Sulfides with Arylzinc Reagents under Mild Conditions
CHEMISTRY-A EUROPEAN JOURNAL
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- 巻
- 20
- 号
- 41
- 開始ページ
- 13146
- 終了ページ
- 13149
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/chem.201404380
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Cross-coupling of general aryl alkyl sulfides with arylzinc reagents proceeds smoothly, even at room temperature or below, with a palladium N-heterocyclic carbene (NHC) catalyst. When combined with reactions that are unique to organosulfurs, that is, the SNAr sulfanylation or Pummerer reaction, the cross-coupling offers interesting transformations that are otherwise difficult to achieve. An alkylsulfanyl group is preferentially converted whilst leaving the tosyloxy and chloro intact, which expands the variety of orthogonal cross-coupling.
- リンク情報
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- DOI
- https://doi.org/10.1002/chem.201404380
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201402269029254886
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/25168477
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000342770900018&DestApp=WOS_CPL
- URL
- http://orcid.org/0000-0002-0153-1888
- ID情報
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- DOI : 10.1002/chem.201404380
- ISSN : 0947-6539
- eISSN : 1521-3765
- J-Global ID : 201402269029254886
- ORCIDのPut Code : 27821804
- PubMed ID : 25168477
- Web of Science ID : WOS:000342770900018