2005年7月
Determination of chemical form of antimony in contaminated soil around a smelter using X-ray absorption fine structure
ANALYTICAL SCIENCES
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- 巻
- 21
- 号
- 7
- 開始ページ
- 769
- 終了ページ
- 773
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.2116/analsci.21.769
- 出版者・発行元
- JAPAN SOC ANALYTICAL CHEMISTRY
Only limited information is available about the behavior of antimony (Sb) in contaminated soils. However, understanding the behavior of Sb in contaminated soils is important, because the toxicity or solubility of this element depends on its chemical state. In this study, we investigated the levels of Sb and the chemical forms of Sb in the soil around a smelter using X-ray absorption fine structure (XAFS) spectra. The highest Sb concentration in the contaminated soil was 2900 mg/kg dry soil. According to Sb-K edge X-ray absorption near edge (XANE) spectra, the Sb in the soil was in the form of Sb(V) compounds. The similarity of extended XAFS (EXAFS) spectra suggests that Sb speciation was independent of the sampling site, which indicates that Sb or Sb2O3 emitted from the smelter was converted into Sb(V) compounds in the soil.
- リンク情報
-
- DOI
- https://doi.org/10.2116/analsci.21.769
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902287515542514
- CiNii Articles
- http://ci.nii.ac.jp/naid/10016579242
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/16038492
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000230465600009&DestApp=WOS_CPL
- ID情報
-
- DOI : 10.2116/analsci.21.769
- ISSN : 0910-6340
- J-Global ID : 200902287515542514
- CiNii Articles ID : 10016579242
- PubMed ID : 16038492
- Web of Science ID : WOS:000230465600009