論文

査読有り
2001年1月

Development of a ground-based LIF instrument for measuring HOx radicals: Instrumentation and calibrations

JOURNAL OF ATMOSPHERIC CHEMISTRY
  • Y Kanaya
  • ,
  • Y Sadanaga
  • ,
  • J Hirokawa
  • ,
  • Y Kajii
  • ,
  • H Akimoto

38
1
開始ページ
73
終了ページ
110
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1023/A:1026559321911
出版者・発行元
SPRINGER

An instrument for measuring tropospheric OH/HO2 radicals by laser-induced fluorescence developed in our laboratory is presented in detail. It is based on FAGE (fluorescence assay by gas expansion) technique and OH is both excited and detected at 308 nm corresponding to its A-X(0,0) band. The alignment of the laser beam, the design of the sample gas inlet, and the devices for the fluorescence detection are optimized so as to reduce the background signal while keeping the OH sensitivity as high as possible. A thermalized position of the expanding gas beam is probed in our system and we did not observe a severe decrease of the HOx sensitivities under humid conditions. An optical fiber is used for delivering the laser light to the fluorescence detection cell mounted outside at a high position. Thus the laser beam alignment is by far simplified and is made highly reproducible, once settled properly. For the calibration, two methods are employed: a system with laser absorption measurements of OH and a system of simultaneous photolysis of H2O and O-2. The calibration factors are compared well within the combined uncertainty. Using the latter system, the conversion efficiency of HO2 to OH by NO addition is measured to be around 90%. The detection limits for OH and HO2 (S/N = 2) are estimated to be 3.3 x 10(6) and 3.6 x 10(6) cm(-)3 at noon, respectively, with an integration time of 1 min. The results of test observations at our institute are also presented.

リンク情報
DOI
https://doi.org/10.1023/A:1026559321911
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000165789100004&DestApp=WOS_CPL
ID情報
  • DOI : 10.1023/A:1026559321911
  • ISSN : 0167-7764
  • eISSN : 1573-0662
  • Web of Science ID : WOS:000165789100004

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