論文

査読有り
2012年

Structural and vibrational relaxations at spontaneous aging in glass

Thermochimica Acta
  • H. Kobayashi and H. Takahashi

532
開始ページ
172-175
終了ページ
175
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.tca.2011.04.029
出版者・発行元
ELSEVIER SCIENCE BV

The entropy change of intermediate-range orders (IROs) through the glass transition is discussed on the basis of the theories developed by Adam-Gibbs and Prigogine. It is estimated that the time dependence of the configurational entropy of glass is zero, but that of its vibrational entropy shows a constant decrease with the smallest change, while maintaining a constant fictive temperature and an isostructural state. It is shown that the spontaneous aging of well annealed glass shows a vibrational relaxation with a long relaxation time, while the annealing and physical aging of glass show a structural relaxation with a short relaxation time. The results indicate that the volume of glass decreases at a constant time rate through spontaneous aging at a constant temperature. It is emphasized that the existence of the constant configurational entropy below the glass transition temperature is the basic feature of glass forming. The nanoorder-size of the IROs in glass determines the residual entropy. The time symmetry in glass is spontaneously violated. The glass transition is a nano-emergence through the abrupt decrease in the fluctuations in the supercooled liquid state. (C) 2011 Elsevier B.V. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.tca.2011.04.029
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000301892500034&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.tca.2011.04.029
  • ISSN : 0040-6031
  • Web of Science ID : WOS:000301892500034

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