論文

査読有り
2004年6月

Thermal equation of state of (Mg0.91Fe0.09)(2)SiO4 ringwoodite

PHYSICS OF THE EARTH AND PLANETARY INTERIORS
  • Y Nishihara
  • ,
  • E Takahashi
  • ,
  • KN Matsukage
  • ,
  • T Iguchi
  • ,
  • K Nakayama
  • ,
  • K Funakoshi

143
開始ページ
33
終了ページ
46
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.pepi.2003.02.001
出版者・発行元
ELSEVIER SCIENCE BV

In situ synchrotron X-ray diffraction (XRD) experiments were conducted using the SPEED-1500 multi-anvil press of SPring-8 on (Mg0.91Fe0.09)(2)SiO4 ringwoodite (Rw), whose composition is similar to that expected in the Earth's mantle transition zone. Pressure-volume-temperature data were collected using a NaCl or MgO capsule up to 21 GPa and 1273 K. A fit to high-temperature Birch-Murnaghan (HTBM) equation of state (EOS) with fixed values of ambient cell volume V-0 = 527.83(7) Angstrom(3) and isothermal bulk modulus K-T0 = 187 GPa yielded a pressure derivative of isothermal bulk modulus K'(T) = 4.41(1), a temperature derivative of bulk modulus (partial derivative(KT)/partial derivativeT)(P) = -0.028(5)GPaK(-1), and a volumetric thermal expansivity alpha = a + bT with values of a = 1.9(2) x 10(-5) K-1 and b = 1.2(4) x 10(-8) K-2. These properties are consistent with the analysis using the thermal pressure (Th-P) EOS. The derived K'(T) and (partial derivativeK(T)/partial derivativeY)(P) are consistent with previous studies on Mg2SiO4 ringwoodite. However, consistent with measurements at 0 GPa, the present equation of state yields significantly higher thermal expansivity than derived by diamond anvil experiments on Mg2SiO4 ringwoodite to 30 GPa and 700 K. On the basis of the equation of state, the density jump around 660 km depth expected for pyrolitic homogeneous mantle (caused by ringwoodite --> Mg-perovskite (MgPv) + magnesiowustite (Mw) and garnet(GRT) --> MgPv transitions) was estimated. The density jump calculated for pyrolite (9.2%) is significantly larger than that across the 660 km discontinuity derived by recent seismolocrical studies (4-6%). One possible explanation for this is that the recent seismic data reflect only the sharp transition concerned with the Rw --> MgPv + Mw transition. (C) 2004, Elsevier B.V. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.pepi.2003.02.001
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000222165200004&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.pepi.2003.02.001
  • ISSN : 0031-9201
  • Web of Science ID : WOS:000222165200004

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