MISC

2008年

銅の電気めっきにおける磁場効果 : スルーホールめっきへの応用

表面技術 = The Journal of the Surface Finishing Society of Japan
  • 森本 良一
  • ,
  • 矢澤 貞春
  • ,
  • 青柿 良一
  • ,
  • 杉山 敦史
  • ,
  • 齋藤 誠

59
6
開始ページ
408
終了ページ
414
記述言語
日本語
掲載種別
DOI
10.4139/sfj.59.408
出版者・発行元
一般社団法人 表面技術協会

In a magnetic field, an electrochemical reaction generates a macroscopic solution flow called MHD flow by the Lorentz force, which enhances mass transfer in the diffusion layer (MHD effect). In electroplating, the MHD effect comes from two-dimensional (2D) nucleation in an electrical double layer accompanied by the unstable growth of non-equilibrium fluctuations (called asymmetrical fluctuations). Electroplating under a magnetic field provides the other magnetic field effect called the micro-MHD effect, which emerges with micro-MHD flow and symmetrical non-equilibrium fluctuations in a diffusion layer, and suppresses three-dimensional (3D) nucleation. That is to say, the MHD effect acts as a positive catalyst, whereas the micro-MHD effect is employed as a negative catalyst, or inhibitor. Furthermore, owing to the strong penetration of the magnetic field into the materials, micro-MHD flows are effectively induced even in the inside of a complicated minute structure. Therefore, by controlling the magnetic field, we can expect high quality plating in the through-hole plating. In this paper, along with its application to through-hole plating, copper magneto-electroplating is examined from various aspects.

リンク情報
DOI
https://doi.org/10.4139/sfj.59.408
CiNii Articles
http://ci.nii.ac.jp/naid/10021170217
CiNii Books
http://ci.nii.ac.jp/ncid/AN1005202X
URL
http://id.ndl.go.jp/bib/9531269
ID情報
  • DOI : 10.4139/sfj.59.408
  • ISSN : 0915-1869
  • ISSN : 1884-3409
  • CiNii Articles ID : 10021170217
  • CiNii Books ID : AN1005202X

エクスポート
BibTeX RIS