2013年9月
Synthesis, Structure, and Function of PCP Pincer Transition-Metal-Complex-Bound Norvaline Derivatives
SYNLETT
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- 巻
- 24
- 号
- 15
- 開始ページ
- 1910
- 終了ページ
- 1914
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1055/s-0033-1339473
- 出版者・発行元
- GEORG THIEME VERLAG KG
A PCP pincer palladium-complex-bound norvaline, Boc-l-[Pd]Nva-OMe, was synthesized and fully characterized by NMR, FT-ICR-MS, and X-ray crystallography. Selective N- and C-terminus transformations of Boc-l-[Pd]Nva-OMe were performed by conventional deprotection-condensation procedures to afford lipophilic palladium-bound norvaline derivatives without metal detachment. The N-/C-bisfunctionalized palladium-bound norvaline showed self-assembly properties, as evidenced by supramolecular gel formation. The catalytic activity of the supramolecular gel was assessed in the 1,4-conjugate addition of phenylboronic acid.
- リンク情報
- ID情報
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- DOI : 10.1055/s-0033-1339473
- ISSN : 0936-5214
- eISSN : 1437-2096
- J-Global ID : 201302248145911474
- Web of Science ID : WOS:000325540000006