2014年4月
Tubular structures bearing channels in organic crystals composed of adamantane-based macrocycles
TETRAHEDRON
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- 巻
- 70
- 号
- 15
- 開始ページ
- 2576
- 終了ページ
- 2581
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.tet.2014.02.006
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
Five macrocyclic molecules (1-5) were efficiently synthesized from the dimerization and trimerization of di-substituted adamantane derivatives, which were composed of three different aromatic units and two different linker groups. Three single-crystals were obtained from these macrocyclic molecules, including a set of pseudopolymorphs (3a and 3b) of macrocycle 3 and another macrocycle 5 (5a). Single crystal Xray analysis revealed that the three monocyclic compounds were rectangular or square in shape with solvent molecules in the cavity. Macrocycle 3 in 3a formed stacks to produce tubular structures with channels that assembled into three-dimensional networks through CH/pi interactions. (C) 2014 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.tet.2014.02.006
- ISSN : 0040-4020
- Web of Science ID : WOS:000334002100010