1996年2月7日
Reaction mechanism of the decomposition of acetic acid on illuminated TiO<inf>2</inf> powder studied by means of in situ electron spin resonance measurements
Langmuir
- ,
- ,
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- 巻
- 12
- 号
- 3
- 開始ページ
- 736
- 終了ページ
- 738
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/la9509615
The existence of methyl radicals in the photo-Kolbe reaction was confirmed by means of in situ measurements with flow electron spin resonance for deuterated acetic acid. From the dependence of the flow rate, two reaction paths were deduced for methyl radical formation. These were assigned to those caused by trapped holes and OH radicals. It is suggested that the former path is dominant when platinum has not been loaded onto TiO2 powder.
- リンク情報
- ID情報
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- DOI : 10.1021/la9509615
- ISSN : 0743-7463
- SCOPUS ID : 0001139883