2016年12月
Investigation of the surface potential of TiO2 (110) by frequency-modulation Kelvin probe force microscopy
NANOTECHNOLOGY
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- 巻
- 27
- 号
- 50
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1088/0957-4484/27/50/505704
- 出版者・発行元
- IOP PUBLISHING LTD
We investigate the surface potential distribution on a TiO2 (110)-1 x 1 surface by Kelvin probe force microscopy (KPFM) and atom-dependent bias-distance spectroscopic mapping. The experimental results demonstrate that the local contact potential difference increases on twofold-coordinated oxygen sites, and decreases on OH defects and fivefold-coordinated Ti sites. We propose a qualitative model to explain the origin of the surface potential of TiO2 (110). We qualitatively calculate the surface potential induced by chemical potential and permanent surface dipole. The calculated results agree with our experimental ones. Therefore, we suggest that the surface potential of TiO2 (110) is dominated not only by the permanent surface dipole between the tip apex atom and surface, but also by the dipoles induced by the chemical interaction between the tip and sample. The KPFM technique demonstrate the possibility of investigation of the charge transfer phenomenon on TiO2 surface under gas conditions. It is useful for the elucidation of the mechanism of the catalytic reactions.
- リンク情報
- ID情報
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- DOI : 10.1088/0957-4484/27/50/505704
- ISSN : 0957-4484
- eISSN : 1361-6528
- Web of Science ID : WOS:000388813200002