2014年4月
Relaxation transition in glass-forming polybutadiene as revealed by nuclear resonance X-ray scattering
JOURNAL OF CHEMICAL PHYSICS
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- 巻
- 140
- 号
- 14
- 開始ページ
- 144906
- 終了ページ
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1063/1.4869541
- 出版者・発行元
- AMER INST PHYSICS
We investigated the arrest mechanism of molecular motions in a glass forming polybutadiene near the glass transition using a new nuclear resonance synchrotron X-ray scattering technique to cover a wide time range (10(-9) to 10(-5) s) and a scattering vector Q range (9.6-40 nm(-1)), which have never been accessed by other methods. Owing to the wide time and Q ranges it was found for the first time that a transition of the a-process to the slow beta-process (or the Johari-Goldstein process) was observed in a Q range higher than the first peak in the structure factor S(Q) at the critical temperature T-c in the mode coupling theory. The results suggest the important roles of hopping motions below T-c, which was predicted by the recent extended mode coupling theory and the cooperative motions due to the strong correlation at the first peak in S(Q) in the arrest mechanism. (C) 2014 AIP Publishing LLC.
- リンク情報
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- DOI
- https://doi.org/10.1063/1.4869541
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201402210113823697
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/24735317
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000334836600037&DestApp=WOS_CPL
- ID情報
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- DOI : 10.1063/1.4869541
- ISSN : 0021-9606
- eISSN : 1089-7690
- J-Global ID : 201402210113823697
- PubMed ID : 24735317
- Web of Science ID : WOS:000334836600037