2005年6月
Raman scattering in CaFeO3 and La0.33Sr0.67FeO3 across the charge-disproportionation phase transition
PHYSICAL REVIEW B
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- 巻
- 71
- 号
- 24
- 開始ページ
- 245110-1
- 終了ページ
- 245110-7
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1103/PhysRevB.71.245110
- 出版者・発行元
- AMERICAN PHYSICAL SOC
Temperature-dependent micro-Raman studies of orthorhombic CaFeO3 and rhombohedral La0.33Sr0.67FeO3 were carried out with an aim to study the role of a lattice in the formation of the charge-disproportioned state (Fe4+-> Fe5++Fe3+) below the transition temperature (T-co) of 290 and 200 K, respectively. Shell-model lattice-dynamical calculations were performed for CaFeO3 to assign the Raman modes and determine their vibrational pattern. The temperature dependence of the peak positions and the peak widths of various modes for both systems show distinct changes across their respective transition temperatures. In CaFeO3, the symmetric-stretching mode at 707 cm(-1) splits into two modes, 707 cm(-1) and 684 cm(-1), corresponding to the breathing-type distortion of the FeO6 octahedra. In comparison, the spectral feature at 704 cm(-1) in La0.33Sr0.67FeO3, which has been assigned to the Raman-forbidden symmetric-stretching mode, disappears below T-co. These observations indicate the presence of finite Jahn-Teller distortions of the FeO6 octahedra in CaFeO3 in the entire temperature range, whereas these distortions are present only above T-co in La0.33Sr0.67FeO3. Two modes at 307 cm(-1) and 380 cm(-1) in La0.33Sr0.67FeO3 approach each other at T-co, indicating a reduction of rhombohedral distortions below T-co.
- リンク情報
- ID情報
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- DOI : 10.1103/PhysRevB.71.245110
- ISSN : 1098-0121
- Web of Science ID : WOS:000230276900036