2005年11月
Study on charge transfer interaction and valence state of layered perovskite-type mixed valence complex [NH(3)(CH(2))(n) NH(3)](2)[(Au(I) I(2))(Au(III)I(4))(I(3))(2)] (n=7, 8), by means of (197)Au Mossbauer spectroscopy
HYPERFINE INTERACTIONS
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- 巻
- 166
- 号
- 1-4
- 開始ページ
- 403
- 終了ページ
- 407
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1007/s10751-006-9300-y
- 出版者・発行元
- SPRINGER
Cs(2)[Au(I)X (2)][Au(III)X (4)](X = Cl, Br, and I) is well known for the three-dimensional perovskite-type gold mixed valence system. Recently, layered perovskite-type gold mixed valence complexes, [NH(3)(CH(2)) (n) NH(3)](2)[(Au(I)I(2))(Au(III)I(4))(I(3))(2)] (n = 7 and 8), have been synthesized. We have investigated the relationship between the structural dimensionality and the Au(I)-Au(III) charge transfer interaction for Cs(2)[Au(I)I(2)][Au(III)I(4)] and [NH(3)(CH(2)) (n) NH(3)](2)[(Au(I)I(2))(Au(III)I(4))(I(3))(2)] (n = 7 and 8) by means of (197)Au Mossbauer spectroscopy.
- リンク情報
- ID情報
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- DOI : 10.1007/s10751-006-9300-y
- ISSN : 0304-3843
- Web of Science ID : WOS:000242969500011