2001年3月
Reversible charge-transfer phase transition in [(n-C3H7)(4)N][(FeFeIII)-Fe-II(dto)(3)](dto = C2O2S2)
SYNTHETIC METALS
- ,
- ,
- ,
- ,
- 巻
- 121
- 号
- 1-3
- 開始ページ
- 1796
- 終了ページ
- 1797
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1016/S0379-6779(00)00839-0
- 出版者・発行元
- ELSEVIER SCIENCE SA
We have investigated the physical properties of [(n-C3H7)(4)N][(FeFeIII)-Fe-II(dto)(3)](dto = C2O2S2) by means of Fe-57 Mossbauer spectroscopy, ESR, and magnetic susceptibility. From the analysis of Fe-57 Mossbauer spectra, we have discovered a new type of first order phase transition for the title complex at about 120 K, where the charge transfer transition between Fe-II and Fe-III occurs reversibly. Moreover, we have found the ferromagnetic phase transition at 6 K.
- リンク情報
- ID情報
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- DOI : 10.1016/S0379-6779(00)00839-0
- ISSN : 0379-6779
- Web of Science ID : WOS:000168831200329