2015年4月
An X-ray investigation of the adsorption of methane, water, and their mixtures in carbon micropores
CARBON
- ,
- ,
- 巻
- 85
- 号
- 開始ページ
- 8
- 終了ページ
- 15
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.carbon.2014.12.043
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
The adsorption of methane and water, and their coexisting state in carbon micropores were investigated by X-ray scattering measurements. The mechanisms of single-component adsorption of water and methane in the carbon micropores proceeded by cluster formation and micropore filling, respectively. The X-ray scattering of the coexisting state reveals that a mesoscopic phase separation occurred in the carbon micropores at 111 K because of the weak interaction between water and methane. At this low temperature, water molecules could not reform hydrogen bonds even with further adsorption of methane molecules. The X-ray scattering measurements provided detailed information on the coexisting state and can be used to study the temperature dependence of the phase behavior of the methane water system during methane hydration formation in nanospaces. (C) 2015 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
-
- DOI : 10.1016/j.carbon.2014.12.043
- ISSN : 0008-6223
- eISSN : 1873-3891
- Web of Science ID : WOS:000349724700002