2019年
LaNi5を用いた CO2とH2からのCH4の生成
Journal of Advanced Science
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- 巻
- 31
- 号
- 開始ページ
- n/a
- 終了ページ
- 記述言語
- 日本語
- 掲載種別
- DOI
- 10.2978/jsas.31101
- 出版者・発行元
- Society of Advanced Science
Methane production from carbon dioxide and hydrogen is known as the Sabatier reaction. However, methanation process by the Sabatier reaction requires high temperatures and high pressures. Therefore, we tried to generate methane by mechanochemical method, using ball-milling as a new methanation process. As a result of ball milling for 3 hours at room temperature, generation of methane was observed. On the other hand, carbon dioxide was consumed more than expected. As for further verification, ball-milling was carried out for 6 hours under carbon dioxide atmosphere. EDX elemental analysis of the milled powder revealed significantly increased carbon content, suggesting the reaction of LaNi5 surface with CO2 followed by the formation of carbides or carbonates of La or Ni. A unique XRD profile was observed in the milled sample, yielding broad amorphous-like peak, possibly from La, and broad peak of Ni. It was shown that ball milling may cause phase separation into La and Ni not only in hydrogen atmosphere but also in carbon dioxide atmosphere.
- リンク情報
- ID情報
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- DOI : 10.2978/jsas.31101
- ISSN : 0915-5651
- CiNii Articles ID : 130007695542