2014年
Detailed Analysis of Sub-Rouse Mode Observed in Polymerized Ionic Liquids with Dynamic Birefringence Measurements
NIHON REOROJI GAKKAISHI
- ,
- 巻
- 42
- 号
- 4
- 開始ページ
- 227
- 終了ページ
- 233
- 記述言語
- 日本語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1678/rheology.42.227
- 出版者・発行元
- SOC RHEOLOGY, JAPAN
Dynamic viscoelasticity and birefringence of two poly(1-butyl-3-vinylimidazolium) based polymerized ionic liquids, PC4VICPFSI and PC(4)VINfO, are investigated by using hand-made shear and tensile rheo-optical apparatus for a further consideration of sub-Rouse mode in polymerized ionic liquids systems. Sub-Rouse mode spectrum for PC4VICPFSI whose counter anions is the same chemical structure as TFSI- and different shape showed the same component function as sub-Rouse mode for PC4VITFSI. On the other hand, sub-Rouse mode spectrum for PC(4)VINfO whose counter anions is the same ionic size as TFSI- but different chemical structure became sharper than that of PC4VITFSI. This result indicated that plasticization effect of counter anions would be more responsible for sub-Rouse mode.
- リンク情報
- ID情報
-
- DOI : 10.1678/rheology.42.227
- ISSN : 0387-1533
- Web of Science ID : WOS:000341673900002