論文

査読有り 国際共著
2021年9月16日

On the crystal stabilization during two-step isothermal crystallization of poly(butylene terephthalate) examined by fast scanning calorimetry

POLYMER
  • Toda, Akihiko
  • ,
  • Furushima, Yoshitomo
  • ,
  • Androsch, Rene
  • ,
  • Schick, Christoph

230
DOI
10.1016/j.polymer.2021.124057
出版者・発行元
ELSEVIER SCI LTD

Crystallization behaviors on two-step isothermal crystallization at T-c1 and T-c2 (< T-c1) were examined by fast scanning calorimetry for poly(butylene terephthalate) in order to identify the dominant process during the secondary stage of crystallization at T-c1 after the completion of spherulitic growth under isothermal condition. From the difference between the melting peaks obtained before and after the low-temperature crystallization step at T-c2, the distinction of the following two processes became realizable: the growth of crystals formed at T(c2 )and the stabilization of crystals formed at T-c1. The dependences on T-c2 and the duration of times Delta t(c1) and Delta t(c2) revealed the following: The formation and growth of new crystals are controlled by thermodynamic driving force determined by supercooling, and hence are suppressed at T-c1 higher than T-c2. The crystal stabilization is controlled by the mobility of polymer chains, and became more pronounced at T-c1. Therefore, the dominant process of the secondary crystallization under isothermal condition at T-c1 should be the stabilization of crystals formed in the primary stage and the formation of new crystals will only have a secondary effect.

リンク情報
DOI
https://doi.org/10.1016/j.polymer.2021.124057
ID情報
  • DOI : 10.1016/j.polymer.2021.124057
  • ISSN : 0032-3861

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