2021年9月16日
On the crystal stabilization during two-step isothermal crystallization of poly(butylene terephthalate) examined by fast scanning calorimetry
POLYMER
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- 巻
- 230
- 号
- DOI
- 10.1016/j.polymer.2021.124057
- 出版者・発行元
- ELSEVIER SCI LTD
Crystallization behaviors on two-step isothermal crystallization at T-c1 and T-c2 (< T-c1) were examined by fast scanning calorimetry for poly(butylene terephthalate) in order to identify the dominant process during the secondary stage of crystallization at T-c1 after the completion of spherulitic growth under isothermal condition. From the difference between the melting peaks obtained before and after the low-temperature crystallization step at T-c2, the distinction of the following two processes became realizable: the growth of crystals formed at T(c2 )and the stabilization of crystals formed at T-c1. The dependences on T-c2 and the duration of times Delta t(c1) and Delta t(c2) revealed the following: The formation and growth of new crystals are controlled by thermodynamic driving force determined by supercooling, and hence are suppressed at T-c1 higher than T-c2. The crystal stabilization is controlled by the mobility of polymer chains, and became more pronounced at T-c1. Therefore, the dominant process of the secondary crystallization under isothermal condition at T-c1 should be the stabilization of crystals formed in the primary stage and the formation of new crystals will only have a secondary effect.
- ID情報
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- DOI : 10.1016/j.polymer.2021.124057
- ISSN : 0032-3861