2000年
Dynamics and rheology of a supercooled polymer melt
STATISTICAL PHYSICS
- ,
- 巻
- 519
- 号
- 開始ページ
- 151
- 終了ページ
- 157
- 記述言語
- 英語
- 掲載種別
- 研究論文(国際会議プロシーディングス)
- 出版者・発行元
- AMER INST PHYSICS
Molecular dynamics simulations are performed for a polymer melt composed of short chains in quiescent and sheared conditions in supercooled states. In quiescent states, while the self chain motions are excellently described by the Rouse model, the stress relaxation function G(t) exhibits a stretched exponential decay in a relatively early stage and ultimately follows the Rouse function. Transient stress evolution after application of shear obeys the linear growth integral(0)(t) dt'G(t') for strain less than 0.1 and then saturates into a non-Newtonian viscosity. A glassy component of the stress is much enhanced as compared to the entropic component.
- リンク情報
- ID情報
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- ISSN : 0094-243X
- Web of Science ID : WOS:000088786100016