2015年
Catalytic asymmetric hydrogenation of quinoline carbocycles: unusual chemoselectivity in the hydrogenation of quinolines
CHEMICAL COMMUNICATIONS
- ,
- ,
- 巻
- 51
- 号
- 35
- 開始ページ
- 7558
- 終了ページ
- 7561
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1039/c5cc01971k
- 出版者・発行元
- ROYAL SOC CHEMISTRY
The reduction of quinolines selectively took place on their carbocyclic rings to give 5,6,7,8-tetrahydroquinolines, when the hydrogenation was conducted in the presence of a Ru(eta(3)-methallyl)(2)(cod)-PhTRAP catalyst. The chiral ruthenium catalyst converted 8-substituted quinolines into chiral 5,6,7,8-tetrahydroquinolines with up to 91 : 9 er.
- リンク情報
- ID情報
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- DOI : 10.1039/c5cc01971k
- ISSN : 1359-7345
- eISSN : 1364-548X
- Web of Science ID : WOS:000353033600035