論文

査読有り
2018年5月1日

Potential of mean force between spherical particles in an ionic liquid and its decomposition into energetic and entropic components: An analysis using an integral equation theory

Journal of Molecular Liquids
  • Ken-ichi Amano
  • ,
  • Tomohiko Hayashi
  • ,
  • Kota Hashimoto
  • ,
  • Naoya Nishi
  • ,
  • Tetsuo Sakka

257
開始ページ
121
終了ページ
131
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.molliq.2018.02.089
出版者・発行元
Elsevier B.V.

We calculate potential of mean force (PMF) between the spherical particles in an ionic liquid by using an integral equation theory, a statistical mechanical theory for liquids. The PMFs between like-charged particles, unlike-charged particles, charged-uncharged particles, and uncharged particles are calculated. Effect of the particle diameter on the PMF is also studied. It is found that the pairs of the like charged particles, unlike charged particles, and uncharged particles are stabilized when they are closely coupled, whereas the charged-uncharged particles are destabilized by the contact. To investigate roles of the energy and entropy in the PMF, it is decomposed into the energetic and entropic components by a temperature differentiation. It is found that the energetic component has relatively high dependency on the surface charges of the immersed particles. On the other hand, the entropic component does not change much upon change in the surface charges of the immersed particles. Generally, an interaction between two particles in an ionic liquid is often explained by the electrostatic and van der Waals interactions, which are classified as the energetic component. However, we found that the entropic component also plays an important role in the interaction.

リンク情報
DOI
https://doi.org/10.1016/j.molliq.2018.02.089
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000430769400012&DestApp=WOS_CPL
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85042941903&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85042941903&origin=inward
ID情報
  • DOI : 10.1016/j.molliq.2018.02.089
  • ISSN : 0167-7322
  • SCOPUS ID : 85042941903
  • Web of Science ID : WOS:000430769400012

エクスポート
BibTeX RIS