2020年7月
Observation of high-pressure bcc phase of titanium at 243GPa
JOURNAL OF APPLIED PHYSICS
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- 巻
- 128
- 号
- 3
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1063/5.0014766
- 出版者・発行元
- AMER INST PHYSICS
In this study, the pressure-induced phase transition of the 3d transition metal titanium (Ti) has been investigated at pressures up to 290GPa at room temperature using an x-ray diffraction technique with a micro-beam. From the analysis of powder x-ray diffraction patterns, the high-pressure delta phase (orthorhombic, Cmcm) was found to transform to the beta phase (body-centered cubic: bcc, Im3m) at 243GPa. Although the volume reduction at this phase transition was less than 1%, the coexistence of the delta phase suggests that the transition is of the first order. The isothermal bulk modulus at zero pressure, B-0, and the pressure derivative of B-0, B-0 ', were estimated to be 125(2)GPa and 3.46(6)GPa, respectively, by least squares fitting to the Vinet equation of state based on the P-V data of the delta and beta phases. This transition to the bcc phase verified predictions from theoretical studies and demonstrated the systematics of the pressure-induced structural phase transition in transition metals.
- リンク情報
- ID情報
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- DOI : 10.1063/5.0014766
- ISSN : 0021-8979
- eISSN : 1089-7550
- Web of Science ID : WOS:000553076500001