論文

査読有り 筆頭著者 責任著者
2018年2月7日

Stereochemical effects on dynamics in two-component systems of gelators with perfluoroalkyl and alkyl chains as revealed by vibrational circular dichroism

Physical Chemistry Chemical Physics
  • Hisako Sato
  • ,
  • Tomoko Yajima
  • ,
  • Akihiko Yamagishi

20
5
開始ページ
3210
終了ページ
3215
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c7cp06264h
出版者・発行元
Royal Society of Chemistry

A mixture of chiral low-molecular weight gelators, (1R,2R)- or (1S,2S)-N,N′-diperfluoroheptanoyl-1,2-diaminocyclohexane (denoted as RR- or SS-CF7, respectively) and (1R,2R)- or (1S,2S)-N,N′-diheptanoyl-1,2-diaminocyclohexane (denoted as RR- or SS-CH7, respectively), was used as a two-component gelator in acetonitrile solvent. The process of gelation was investigated by time-step vibrational circular dichroism (VCD) spectroscopy. The method enabled us to study the dynamical behavior of CF7 and CH7 molecules independent of their characteristic vibrational bands. We focused on the effects of the chirality relation between the two gelators. In the case of the enantiomeric mixtures (RR-CF7/RR-CH7 or SS-CF7/SS-CH7), the two components exhibited different time-courses in their VCD spectra. As for CF7, the couplet peak intensities assigned to CO stretching increased with time, while those for CH7 remained low. In the case of the racemic mixture (RR-CF7/SS-CH7 or SS-CF7/RR-CH7), the intensities of the peaks assigned to the CO stretching vibration for both CF7 and CH7 molecules maintained a constant level with time. The VCD results were compared with the SEM images of the freeze-dried gel samples taken at various time intervals. Furthermore, the mechanisms for the gelation of two-component systems are discussed.

リンク情報
DOI
https://doi.org/10.1039/c7cp06264h
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/29075736
ID情報
  • DOI : 10.1039/c7cp06264h
  • ISSN : 1463-9076
  • PubMed ID : 29075736
  • SCOPUS ID : 85041665169

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