2001年12月
Remarkable effect of aluminum reagents on rearrangements of epoxy acylates via stable cation intermediates and its application to the synthesis of (S)-(+)-sporochnol A
JOURNAL OF ORGANIC CHEMISTRY
- ,
- ,
- ,
- ,
- ,
- ,
- 巻
- 66
- 号
- 26
- 開始ページ
- 8779
- 終了ページ
- 8786
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/jo0104328
- 出版者・発行元
- AMER CHEMICAL SOC
A remarkable effect of (C6F5O)(3)Al for promoting the rearrangement of epoxy acylates via stable cation intermediates was found, and new methods for constructing chiral benzylic, vinylic, and acetylenic quaternary carbon centers were developed. During the study, the importance of the ionic nature of the O-metal bond in the intermediates of such epoxides was addressed. This method was applied to the asymmetric total synthesis of (S)-(+)-sporochnol A.
- リンク情報
- ID情報
-
- DOI : 10.1021/jo0104328
- ISSN : 0022-3263
- Web of Science ID : WOS:000172993000011