論文

2002年12月18日

Electroauxiliary-assisted sequential introduction of two carbon nucleophiles on the same α-carbon of nitrogen: Application to the synthesis of spiro compounds

Journal of the American Chemical Society
  • Seiji Suga
  • ,
  • Mitsuru Watanabe
  • ,
  • Jun ichi Yoshida

124
50
開始ページ
14824
終了ページ
14825
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ja028663z

The sequential introduction of two carbon nucleophiles on the same α-carbon of nitrogen by using selective oxidative cleavage of two silyl groups as electroauxilialies has been accomplished. The combination of this expedient transformation and ring-closing metathesis enables reliable and straightforward syntheses of nitrogen-containing spiro compounds, such as cephalotaxine. Copyright © 2002 American Chemical Society.

リンク情報
DOI
https://doi.org/10.1021/ja028663z
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/12475305
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0037132624&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=0037132624&origin=inward
ID情報
  • DOI : 10.1021/ja028663z
  • ISSN : 0002-7863
  • PubMed ID : 12475305
  • SCOPUS ID : 0037132624

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