2002年12月18日
Electroauxiliary-assisted sequential introduction of two carbon nucleophiles on the same α-carbon of nitrogen: Application to the synthesis of spiro compounds
Journal of the American Chemical Society
- ,
- ,
- 巻
- 124
- 号
- 50
- 開始ページ
- 14824
- 終了ページ
- 14825
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja028663z
The sequential introduction of two carbon nucleophiles on the same α-carbon of nitrogen by using selective oxidative cleavage of two silyl groups as electroauxilialies has been accomplished. The combination of this expedient transformation and ring-closing metathesis enables reliable and straightforward syntheses of nitrogen-containing spiro compounds, such as cephalotaxine. Copyright © 2002 American Chemical Society.
- リンク情報
- ID情報
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- DOI : 10.1021/ja028663z
- ISSN : 0002-7863
- PubMed ID : 12475305
- SCOPUS ID : 0037132624