論文

査読有り
2019年12月24日

Negative ionic states of tin in the oxide superconductor Sr3−xSnO revealed by Mössbauer spectroscopy

Physical Review B
  • Atsutoshi Ikeda
  • ,
  • Shun Koibuchi
  • ,
  • Shinji Kitao
  • ,
  • Mohamed Oudah
  • ,
  • Shingo Yonezawa
  • ,
  • Makoto Seto
  • ,
  • Yoshiteru Maeno

100
24
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1103/PhysRevB.100.245145
出版者・発行元
AMER PHYSICAL SOC

We report the temperature variation of the Sn-119-Mossbauer spectra of the antiperovskite (inverse perovskite) oxide superconductor Sr3-xSnO. Both superconductive (Sr deficient) and nonsuperconductive (nearly stoichiometric) samples exhibit major gamma-ray absorption with an isomer shift similar to that of Mg2Sn. This fact shows that Sr3-xSnO contains the metallic anion Sn4-, which is rare, especially among oxides. In both samples, we observed another gamma-ray absorption with a larger isomer shift, indicating that there is another ionic state of Sn with a higher oxidation number. The temperature dependence of the absorption intensities reveals that the Sn ions exhibiting larger isomer shifts have a lower energy of the local vibration. The larger isomer shift and lower vibration energy are consistent with the values estimated from the first-principles calculations for hypothetical structures with various Sr-deficiency arrangements. Therefore, we conclude that the additional gamma-ray absorptions originate from the Sn atoms neighboring the Sr deficiency.

リンク情報
DOI
https://doi.org/10.1103/PhysRevB.100.245145
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000504446200006&DestApp=WOS_CPL
ID情報
  • DOI : 10.1103/PhysRevB.100.245145
  • ISSN : 2469-9950
  • eISSN : 2469-9969
  • ORCIDのPut Code : 66470177
  • Web of Science ID : WOS:000504446200006

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