The opacity information of a finite-temperature plasma is an important property and requires the population distribution of a given plasma condition. A population kinetic code for plasma spectroscopy, FLYCHK, has been widely used by researchers to study the spectroscopic properties of high-energy-density plasmas under a wide range of conditions. In this study, the FLYCHK calculation of the Planck and Rosseland mean opacities of low- to high-Z elements, such as aluminum (Z = 13), iron (Z = 26), and gold (Z = 79), under a wide temperature and density range (T = 10−3–102 keV, ρ = 10−6–102 g/cc) is reported. This study mainly focused on the quantitative comparisons of FLYCHK opacities with commonly used opacities: ATOMIC and PROPACEOS. Comparisons show that the FLYCHK mean opacities are comparable to other results over a wide range of plasma conditions. Aluminum opacities were analyzed in detail to understand the characteristics of FLYCHK opacity simulations.