The neutron capture cross sections for Pb-207,Pb-208 have been measured in the neutron energy region from 10 to 110 key. The gamma-rays cascaded from a capture state to the ground state or low-lying states of Pb-208,Pb-209 were observed for the first time, using an anti-Compton NaI(Tl)) spectrometer and a TOP method. The observed discrete gamma-ray energy spectra enabled us to determine neutron capture cross sections for Pb-207,Pb-208 with small systematic errors, since we could distinguish gamma-ray of Pb-207,Pb-208(n, gamma) reactions from background gamma-ray with use of the gamma-ray spectra. The obtained cross sections include both contributions of resonance and direct capture components different from the previous TOP measurements.