1999年1月
Molecular rotation in an antiferroelectric liquid crystal studied by C-13-Nuclear magnetic resonance spin-lattice relaxation time measurement
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS
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- 巻
- 38
- 号
- 1A
- 開始ページ
- 147
- 終了ページ
- 150
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1143/JJAP.38.147
- 出版者・発行元
- JAPAN J APPLIED PHYSICS
Temperature dependence of the spin-lattice relaxation time T-1 was measured in an antiferroelectric liquid crystal, 4-(1-methylheptyloxycarbonyl) phenyl-4'-octyloxybiphenyl-4-carboxylate (MHPOBC) by means of C-13-nuclear magnetic resonance (NMR). The activation energies determined by the temperature dependence of T-1 are the same for most of the carbon nuclei in the SmA and SmCA* phases, whereas they are different for carbon nuclei at the chiral center and at the carbonyl carbons. The rotational correlation time changes continuously through the phase change from SmA to SmCA*. Critical slowing down of the molecular rotatioin was not observed.
- リンク情報
- ID情報
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- DOI : 10.1143/JJAP.38.147
- ISSN : 0021-4922
- Web of Science ID : WOS:000079477600031