論文

1999年1月

Molecular rotation in an antiferroelectric liquid crystal studied by C-13-Nuclear magnetic resonance spin-lattice relaxation time measurement

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS
  • K Tokumaru
  • ,
  • B Jin
  • ,
  • S Yoshida
  • ,
  • Y Takanishi
  • ,
  • K Ishikawa
  • ,
  • H Takezoe
  • ,
  • A Fukuda
  • ,
  • T Nakai
  • ,
  • S Miyajima

38
1A
開始ページ
147
終了ページ
150
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1143/JJAP.38.147
出版者・発行元
JAPAN J APPLIED PHYSICS

Temperature dependence of the spin-lattice relaxation time T-1 was measured in an antiferroelectric liquid crystal, 4-(1-methylheptyloxycarbonyl) phenyl-4'-octyloxybiphenyl-4-carboxylate (MHPOBC) by means of C-13-nuclear magnetic resonance (NMR). The activation energies determined by the temperature dependence of T-1 are the same for most of the carbon nuclei in the SmA and SmCA* phases, whereas they are different for carbon nuclei at the chiral center and at the carbonyl carbons. The rotational correlation time changes continuously through the phase change from SmA to SmCA*. Critical slowing down of the molecular rotatioin was not observed.

リンク情報
DOI
https://doi.org/10.1143/JJAP.38.147
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000079477600031&DestApp=WOS_CPL
ID情報
  • DOI : 10.1143/JJAP.38.147
  • ISSN : 0021-4922
  • Web of Science ID : WOS:000079477600031

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