2016年11月
Transitional subphases near the electric-field-induced phase transition to the ferroelectric phase in Se-containing chiral smectic liquid crystals observed by resonant x-ray scattering
PHYSICAL REVIEW E
- ,
- ,
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- 巻
- 94
- 号
- 5
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1103/PhysRevE.94.052703
- 出版者・発行元
- AMER PHYSICAL SOC
Resonant x-ray scattering experiments revealed transitional subphases near the electric-field-induced phase transition of a Se-containing chiral liquid crystal in a planar aligned cell geometry. In the lower-temperature range (Sm-C-A(*) and three-layer periodicity Sm-C-gamma(*) phases), the six-layer periodicity subphase appeared with increasing electric field during the field-induced transition from Sm-C-gamma(*) to Sm-C-gamma(*). In the higher-temperature range [four-layer periodicity antiferroelectric (AF) phase], the peak positions of the three-layer satellites shifted to those of the four-layer satellites and then the satellites corresponding to the five-through seven-layer periodicity appeared in sequence. Near the AF to Sm-C-gamma(*) a phase transition temperature, the layer periodicity increased with applied field. The molecular configurations of the subphases near the field-induced transition are discussed based on the Ising, distorted clock, and perfect clock models.
- リンク情報
- ID情報
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- DOI : 10.1103/PhysRevE.94.052703
- ISSN : 2470-0045
- eISSN : 2470-0053
- Web of Science ID : WOS:000388276800009