2020年10月
Ni-Pt Alloy Nanoparticles with Isolated Pt Atoms and Their Cooperative Neighboring Ni Atoms for Selective Hydrogenation of CO2 Toward CH4 Evolution: In Situ and Transient Fourier Transform Infrared Studies
ACS APPLIED NANO MATERIALS
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- 巻
- 3
- 号
- 10
- 開始ページ
- 9633
- 終了ページ
- 9644
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acsanm.0c01570
- 出版者・発行元
- AMER CHEMICAL SOC
We elucidated the cooperative active sites of Ni-Pt alloy nanoparticles composed of Pt atoms isolated by Ni atoms and their neighboring Ni atoms for the efficient and selective hydrogenation of CO2 toward CH4. The stepwise methanation dynamics were revealed by in situ observations and transient changes in the infrared spectra during the hydrogenation of CO2. It was found that the hydrogenation of CO species attached to the isolated Pt atoms proceeded through a bridging CO species between isolated Pt atoms and their neighboring Ni atoms, leading to an excellent selectivity toward CH4. Kinetic studies revealed that the high H-2 dissociation ability of the Pt species accelerated the hydrogenation of the carbon species over the surface of the NiPt alloy, thereby avoiding the rate limitations of CH4 formation which are common for Ni catalysts. The bifunctional role of the isolated Pt atoms therefore allowed the efficient formation of CH4 while maintaining the excellent selectivity of the Ni catalyst toward CH4, despite Pt catalysts tending to favor CO production.
- リンク情報
- ID情報
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- DOI : 10.1021/acsanm.0c01570
- ISSN : 2574-0970
- ORCIDのPut Code : 80537534
- Web of Science ID : WOS:000583331600068