2018年10月
Synthesis and chiroptical properties of phenanthrene-fused N2O-type BODIPYs
Tetrahedron Letters
- ,
- ,
- ,
- ,
- 巻
- 59
- 号
- 47
- 開始ページ
- 4149
- 終了ページ
- 4152
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1016/j.tetlet.2018.10.003
- 出版者・発行元
- Elsevier
A series of phenanthrene-fused N2O-type boron-dipyrrin complexes (BODIPYs) with various substituents were synthesized. The synthesized BODIPYs show light absorption and emission in the red to near-infrared region due to their extended it pi-system. Furthermore, the first optical resolution of the N2O-type BODIPY was achieved using the phenyl-substituted complex. The separated enantiomers are stable to racemization at room temperature, and exhibited a Cotton effect in the deep-red region. (C) 2018 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.tetlet.2018.10.003
- ISSN : 0040-4039