2017年3月
Copper-catalyzed Selective Oxygenation of Methyl and Benzyl Substituents in Pyridine with O-2
CHEMISTRY LETTERS
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- 巻
- 46
- 号
- 3
- 開始ページ
- 348
- 終了ページ
- 350
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.161074
- 出版者・発行元
- CHEMICAL SOC JAPAN
A selective oxygenation of picolines and their derivatives has been achieved by using a simple copper salt as a catalyst and molecular oxygen as an oxidant, where the alpha-position of the alkyl substituent is selectively oxidized to give the corresponding aldehydes or ketones. Addition of a catalytic amount of water enhances the catalytic activity, which could be attributed to the role of the proton donor to activate the substrates.
- リンク情報
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- DOI
- https://doi.org/10.1246/cl.161074
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000396062600005&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-85012869286&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0003-2002-5582
- ID情報
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- DOI : 10.1246/cl.161074
- ISSN : 0366-7022
- eISSN : 1348-0715
- ORCIDのPut Code : 40737480
- SCOPUS ID : 85012869286
- Web of Science ID : WOS:000396062600005